
INFLUENCE OF NANO-CCTO FILLERS ON THE DIELECTRIC CONSTANT OF EPOXY COMPOSITES
Mukhlis M. Ismai , Physical, School of Applied Sciences /University of Technology, IraqAbstract
The incorporation of nano-sized Calcium Copper Titanate (nano-CCTO) fillers into epoxy composites has been shown to significantly impact their dielectric properties. This study investigates the influence of varying concentrations of nano-CCTO on the dielectric constant of epoxy composites, focusing on understanding how these fillers alter the electrical behavior of the matrix material. Nano-CCTO particles, known for their high dielectric permittivity and low dielectric losses, were synthesized and incorporated into an epoxy resin at different weight fractions. The dielectric properties of the resulting composites were characterized using impedance spectroscopy over a broad frequency range. The study reveals that the dielectric constant of the epoxy composites increases with the addition of nano-CCTO fillers, with the most pronounced effects observed at specific filler concentrations. The observed improvements in dielectric properties are attributed to the enhanced polarization effects and the formation of a percolation network within the composite matrix. These findings suggest that nano-CCTO fillers can be effectively used to tailor the dielectric properties of epoxy composites for advanced electronic and electrical applications.
Keywords
Nano-CCTO, epoxy composites, dielectric constant
References
M.A. Subramanian, L.D. Duan, B.A. Reisner, and A.W. Sleight, High dielectric constant in ACu3Ti4O12 and ACu3Ti3FeO12 phases, Journal Solid State Chemistry , 151, 2000, 323-325.
C.C. Homes, Vogt, T. Shapiro, S. Wakimoto, and A.P. Ramirez, Optical Response of High-Dielectric-Constant Perovskite-Related Oxide, Science, 293, 2001, 673-676.
D.C. Sinclair, T.B.Adams, F.D. Morrison, and A.R. West, CaCu3Ti4O12: One-step internal Barrier Layer Capacitor.,Applied physics . Lett. 80(12), 2002, 2153-2155.
Li, W. Schwartz, and R.W. , Maxwell-Wagner relaxations and their contributions to the high permittivity of calcium copper titanate ceramics, phys. Rev B 75(1) , 2007, 012104.
P. Lunken Heimer, V. Bobnar , A.V .Pronin, A.I. Ritus, A.A. Volkov, and A.Loidl, Origin of apparent colossal dielectric constants, Pysical Revlew, B 66, 2002, 052105.
P. Lunken Heimer, R. Fichtl , S.G. Ebbinghaus,and A.Loidl, Non-intrinsic origin of the Colossal Dielectric Constants in CaCu3Ti4O12, Phys. Rev. B70, 2004, 172102.
R.N. Choundhary, and U.Bhunia, Structural, dielectric and electrical properties of ACu3Ti3FeO12 (A = Ca, Sr and Ba), Journal of Materials Science37, 2002, 5177-5182.
R.K. Grubbs, E.L. Venturini, P.G. Clem, J.J. Richardson , B.A. Tuittle, and G.A. Samara, Dielectric and magnetic properties of Feand Nb-doped CaCu3Ti4O12, phys. Rev. B72(10), 2005, 104111.
L.He, J.B. Neaton, M.H. Cohen, D.Vanderbit, and C.C. Homes, First-principles study of the structure and lattice dielectric response of CaCu3Ti4O12 Phys. Rev. B 65(21), 2002, 214112.
P.Lunkenheimer, R.Ficht, S.G. Ebbinghaus, and A.Loidl, Evidence for power-law frequency dependence of intrinsic dielectric response in the CaCu3Ti4O12, Phys. Rev. B70, 2004, 172102.
L.Liu, H.Fan, P.Fang, and L.Jin, Fast densification and electrical conductivity of yttriastabiize dzirconianano ceramics ,Solid State Comm.142, 2007, 573-576.
A.P. Ramirez, M.A. Subramanian, M.Gardel, G.Blumberg, D.Li, T.Voget, and S.M. Shapiro, Giant dielectric constant response in a copper-titanate , Solid State Communications, (115), 2000, 217-220.
Z.Y. Cheng, Q.M. Zhang, and F.B. Bateman , Dielectric relaxation behavior and its relation to microstructure in relaxor ferroelectric polymers: High-energy electron irradiated poly(vinylidene fluoride–trifluoroethylene) copolymers, Journal Applied Physics, 92(11), 2002, 6749.
X. Zhang, C. L. Pint, M. H. Lee, B. E. Schubert, A. Jamshidi, K. Takei, H. Ko, A. Gillies, R. Bardhan, J. J. Urban, M. Wu, R. Fearing, and A. Javey. ,Optically- and Thermally-Responsive Programmable Materials Based on Carbon Nanotube-Hydrogel Polymer Composites, Nano Letters,11, 2011, 3239-3244.
Article Statistics
Downloads
Copyright License
Copyright (c) 2024 Mukhlis M. Ismai

This work is licensed under a Creative Commons Attribution 4.0 International License.