This article focuses on the study of alkylation reactions of p-nitrophenol in the presence of nanocatalysts. The formation of C-alkyl and O-alkyl products was observed in the alkylation reactions and the composition of isomers was determined. Benzyl chloride was selected as the best alkylating agent for the reactions, and alkylation under mild conditions gives mainly O-benzyl products. As a catalyst, TiO₂·SiO₂/FeCl₃ catalyst, FeCl₃ nanocatalyst soaked in polyvinyl chloride (PVC) was used and it was found that the selectivity increased.

p-nitrophenol, benzyl chloride, PVC-based FeCl3 nanocatalyst, nanostructured TiO2·SiO2/FeCl3 catalyst

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