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MODIFICATION OF POLYTETRAFLUOROETHYLENE BY COPOLYMERIZATION OF TETRAFLUOROETHYLENE WITH VINYL ALCOHOL IN THE PRESENCE OF LOW-TEMPERATURE INITIATOR DIPDC

Yakubov Ilkham Yuldashevich , Associate Professor of the Chemistry Department of Fergana State University

Abstract

The present study focuses on the modification of polytetrafluoroethylene (PTFE) by copolymerization of tetrafluoroethylene (TFE) with vinyl alcohol (VA) using a low-temperature initiator DIPDC (Diisopropyl peroxydicarbonate). PTFE is widely known for its exceptional chemical resistance, thermal stability, and low friction coefficient, but its inherent inertness limits its adhesion and surface modification potential. Through copolymerization with VA, functional hydroxyl groups can be introduced into the polymer chain, enhancing the material's reactivity and surface properties. This paper describes the synthesis process, characterization of the copolymers, and the impact of this modification on PTFE properties.

Keywords

Polytetrafluoroethylene, Tetrafluoroethylene, Vinyl Alcohol, Copolymerization, DIPDC, Low-temperature initiator, Polymer modification.

References

Ebnesajjad, S. (2013). Fluoroplastics. 2nd Edition, William Andrew Publishing.

Hougham, G., Cassidy, P. E., Johns, K., Davidson, T. (1999). Fluoropolymers: Synthesis and Applications. Springer.

Gangal, S. V., et al. (2018). Polymer Surface Modification: Relevance to Adhesion. CRC Press.

Brydson, J. A. (1999). Plastics Materials. Butterworth-Heinemann.

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MODIFICATION OF POLYTETRAFLUOROETHYLENE BY COPOLYMERIZATION OF TETRAFLUOROETHYLENE WITH VINYL ALCOHOL IN THE PRESENCE OF LOW-TEMPERATURE INITIATOR DIPDC. (2025). International Journal of Artificial Intelligence, 5(06), 1738-1740. https://www.academicpublishers.org/journals/index.php/ijai/article/view/5500